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Fayl:Dichloromethane near IR spectrum.png

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English: Dichloromethane near IR spectrum. I took this spectrum using an Ocean Optics near IR (NIR-512) temperature-regulated InGaAs detector spectrometer [1] with IR fiber optic light guide. This is a very rough spectrum and should not be used for any kind of quantitative data whatsoever. I took it by shining the light from a halogen lightbulb through a tiny (~20ml) beaker of liquid dichloromethane (~2cm liquid optical path) and into the fiber optic of the spectrometer (I subtracted the spectrum of the empty beaker before taking this one). The spectrometer was not really intended to be used this way and it is a very sloppy way to take a spectrum! Nonetheless, based on comparing it to simillarly taken spectra of water and ethanol, I think it likely fairly accurately shows real features of the NIR spectrum of this compound. I normalized the transmittance to 100%.
Sanasi 10 sentyabr 2006 (original upload date)
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Original upload log

The original description page was here. All following user names refer to en.wikipedia.
  • 2006-09-16 23:30 Deglr6328 3500×2441×8 (387879 bytes) transmittance
  • 2006-09-10 01:02 Deglr6328 3500×2441×8 (385954 bytes) oops. missing numbers
  • 2006-09-10 00:54 Deglr6328 3500×2441×8 (432400 bytes) Dichloromethane near IR spectrum. I took this spectrum using an Ocean Optics HR4000 spectrometer [http://www.oceanoptics.com/] with IR fiber optic light guide. This is a very rough spectrum and should not be used for any kind of quantitative data whatsoev

Unfortunately, this spectrum is quite inaccurate. Please do NOT trust it. The author claims it to be a NIR spectrum of dichloromethane, whereas it is in fact in the mid-IR region which is officiallly from 4000 cm-1 to 400 cm-1. There are many strange absorption bands in this spectrum that cannot be attributed to pure CH2Cl2. This may be a result of the author's use of a spectrometer and detector intended for the NIR which extends from approximately 12,500 cm-1 to 4000 cm-1. The author describes it as a "very rough spectrum", but it is in fact totally misleading as to the position and number of IR absorption bands. A true mid-IR spectrum of dichloromethane using a professional FTIR spectrometer, with or without an ATR accesory, produces much more reliable results that agree with literature data.

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